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Ciments Molins: Conclusions

The waste heat recovery technology has been tested by these five different prototypes with different variations in power electronics, thermal collector contact surfaces, cooling system and the thermoelectric generators to configure the best option for each type of heat source.

Efficiency is one of the main parameters analysed in each project. This parameter shows how much energy is extracted from waste heat.

The efficiency of the prototype depends on the heat source, the heat collector type and the cooling system applied.

The activity of Ciments Molins Group focuses on manufacturing, distributing and selling cement, concrete, mortars, aggregates and concrete prefabricates, and running activities and production plants in different countries.

The energy recovery system (Heat R-System) installed in the industrial plant that Ciments Molins has in St. Vicenç dels Horts (Barcelona) makes use of the waste heat generated in the walls of the rotatory kiln used for firing the clinker and which are close to the burner.

The operating cycle of the rotatory kiln is 24 hours a day, 7 days a week, and the heat source temperature is about 200 ºC although the temperature inside the rotatory kiln is up to 1000ºC. The device must withstand ambient temperatures up to 40 ºC.

The recovery system obtains heat by conduction and is non-intrusive.

The forced air generated by fans cools the equipment to obtain the maximum temperature difference between the two sides of the Peltier cells.

In this project, the energy recovery system is based on a new type of WHRU:

 

WHRU – HSCD100

 

 

  • Cooling system principle: Forced air convention
  • Cooling components Heat sink with four fans.
  • Heat capture system principle Conduction
  • Thermal collector Plane thermal collector.
  • Electrical energy generator Thermoelectric generator TEG – Peltier cell
  • Peltier cell number 36 cells 40 *40 mm

 

The main feature of this device is that it groups a set of 36 thermoelectric generators into a single unit. This design was created to group as many thermoelectric generators as possible in the smallest possible space, optimising the ratio of power generated per unit area.

 

Results

 

Heat source temperature 191 – 213 ºC
Generation area WHRU 1705.7 cm2
Mean power generated 5.43 W
Maximum power generated 6.86 W
Energy generated 47.6 kWh/year
Power density 31.83 W/m2
Heat dissipated by the square heat source 310 W
Heat flow through Heat R-System by conduction 491 W
Efficiency 1.40 %

 

Prototypes based on a forced air-cooling system with a heat collector in contact with a hot surface have been found to be the least effective and efficient.

To generate more energy, it is necessary to capture the maximum amount of heat flow. This is possible if the system is intrusive and there is contact between the fins of the heat collector and the hot gases. At Ciments Molins, the system is non-intrusive and the heat is obtained by surface contact between the heat collector and the hot wall of the rotary kiln.

On the other hand, there is a higher heat transfer due to the higher number of Peltier cells mounted.

Unlike the forced water-cooling system, the forced air-cooling system cannot absorb all the heat. This means that there is no temperature difference between the sides of the Peltier cells and the efficiency is lower.

Gomà Camps Paper Industry: Conclusions

The waste heat recovery technology has been tested by these five different prototypes with different variations in power electronics, thermal collector contact surfaces, cooling system and the thermoelectric generators to configure the best option for each type of heat source.  

Efficiency is one of the main parameters analysed in each project. This parameter shows how much energy is extracted from waste heat.  

The efficiency of the prototype depends on the heat source, the heat collector type and the cooling system applied. 

In the paper industry tissue paper dryers are well known. They are equipped with a hood that blows hot air at high speed against the tissue paper and a rotating drying cylinder called Yankee that is partially covered by the hood. The tissue paper is dried by combining the drying cylinder that transfers heat by contact from the superheated steam circulating inside and the hood that dries by heat and mass transfer. 

The energy recovery system (Heat R-System) installed in the tissue paper manufacturing plant that Gomà-Camps has in La Riba (Tarragona) makes use of the waste heat generated in a tissue paper dryer.  

The operating cycle of the dryer is 24 hours a day, 7 days a week, and the gas temperature varies from 200 to 240 ºC. The device must withstand ambient temperatures up to 40 ºC and sun exposure. 

The recovery system that is installed is intrusive: the fins of the WHRU thermal collectors are installed inside the chimney to capture the maximum amount of heat from the gases. Although intrusive, this system does not affect the operation of the dryer, as it does not cause any pressure drop or condensation. 

WHRU modules uses water heat-exchanger (water-block) for their cooling to obtain the maximum temperature difference between the two sides of the Peltier cells. The water is pumped from a tank. The pump used to pump the cooling water to the water blocks works so long as the Yankee dryer does. The water-cooling temperature is 14-20 ºC.  

In this project, the energy recovery system is based on a new type of WHRU: 

 

WHRU -WBCV100

 

 

  • Cooling system principle: Forced water convention  
  •  Cooling components Cold plate or water heat exchanger (waterblock).  
  • Heat capture system principle Forced air convection – gas exhaust.  
  • Thermal collector Intrusive convectional heat sink  
  • Electrical energy generator Thermoelectric generator TEG – Peltier cell 
  • Peltier cell number 6 cells 40 *40 mm 

 

 

Gas temperature 200-240 ºC
Generation area two WHRU 531 cm2
Mean power generated 17.5 W
Maximum power generated 25.92 W
Energy generated 153.30 kWh/year
Power density 329.40 W/m2
Heat flow in the exhaust gas 2.31 MW
Heat flow through Heat R-System 813.20 W
Efficiency 3.19 %

 

 

Results

 

In terms of power generation, this device produces more electrical energy per surface area than the prototype installed at Bodegas Torres. Consequently, its efficiency is higher. However, unlike a solar panel that has a system efficiency of approximately 20 %, the heat recovery system installed in Goma-Camps has a system efficiency of approximately 3%.  

 

– To generate more energy, it is necessary to capture the maximum amount of heat flow. Therefore, the contact surface between the heat collectors and the hot gases should be as large as possible. Therefore, the installation of the fins in contact with the gas increases the energy generation. However, the length of the fins is limited because a longer length could lead to a pressure drop in the gas flow which could cause emission problems in the installation. 

 

-From the standpoint of the installation, the water-cooling system requires a hydraulic loop with a pump. It is essential to ensure a continuous supply of cooling water to avoid damaging the prototype by exceeding the maximum working temperatures of the components. Therefore, installing two pumps instead of one or automating the start-up of the pump when the process starts are options to ensure the water supply. 

 

On the other hand, the quality of the water supply is important. The water must be free of suspended solids to avoid possible clogging that could hinder or prevent the water supply and thus damage the equipment. Therefore, Goma-Camps linked the pump operation to the dryer. In this way, the water pump works while the dryer is working. 

  

-The Yankee cylinder is used in all paper manufacturing factory. Therefore, Goma – Camps is completely scalable to install waste heat recovery systems in other paper manufacturing companies. 

Ciments Molins: Pilot Installation

The installation was carried out on May 31, 2021 and on September 28, 2021.

The final installation of the recovery system was performed jointly with the staff of AEInnova and Ciments Molins.

Below you can see some of the photographs taken at the installation.

 

Distiller Chemical Industry: Pilot Installation

The installation was carried out on December 24, 2020.

The installation of the pilot required mechanical works that were performed by a specialized company following the instructions of the mechanical department of AEInnova.

The final installation of the recovery system was performed jointly with the staff of AEInnova and Distiller.

Below you can see some of the photographs taken at the installation.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Ciments Molins Cement Industry: Prototype Implementation

All components of the heat recovery system are integrated and connected to generate the maximum amount of power from the waste heat source.

The heat recovery system requires a cooling system for proper operation and to avoid thermal collapse of the system. Thus, in Ciments Molins the prototype uses four fans to generate forced air.

 

Figure. Fan

Celsa Steel Industry: Prototype Design

It is proposed to install 1 WHRU module that take advantage of the heat emitted by the blank beam during their cooling process.

This module will be fixed on a metal plate that captures the maximum possible radiation from the hot beam. The WHRU module will transform the heat gathered by this metal plate into electricity.

This plate is installed onr a U-shaped support that will be placed 50 cm from the ejection zone of the blank beam.

 

 

Ciments Molins Cement Industry: Prototype Design

LOCATION

It is proposed to install 1 WHRU module in one of the walls of the clinker rotary kiln of the facility. The temperature inside the clinker rotary kiln is about 1450 ° C, but the WHRU will take heat by conduction from the wall of the clinker rotary kiln that is around 200 ° C.

 

Figure 1-Installation place-Wall of the clinker rotatory kiln

Keraben Ceramics Industry: Technical Visit

In order to start a thermoelectricity project, it is important to have a physical visit to the facilities in order to determine the waste heat ranges and the temperature in addition to the installation of the WHRU system.  The technical visit was made at Keraben (Castellón) on Dec 9th, 2019.

Celsa Steel Industry: Technical Visit

In order to start a thermoelectricity project, it is important to have a physical visit to the facilities in order to determine the waste heat ranges and the temperature in addition to the installation of the WHRU system.  The technical visit was made at Celsa (Castellbisbal, Barcelona) on May 11, 2018.

Ciments Molins Cement Industry: Technical Visit

In order to start a thermoelectricity project, it is important to have a physical visit to the facilities in order to determine the waste heat ranges and the temperature in addition to the installation of the WHRU system.  The technical visit was made at the Cementos Molins (St. Vicenç del Horts, Barcelona) on Juny 29th, 2018.

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